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November 2003

Education

 


Back to basics the only way forward in understanding organic chemistry

Deepa Mahajan, Botswana

Organic chemistry is not such a tough subject to learn for exams argues Deepa Mahajan from Botswana. Across the world students rate chemistry as being a difficult subject to learn and for many, organic chemistry tends to be the toughest. This is true of her students in Botswana. But why bother with organic chemistry, you may ask? If you ever plan to study in the health sciences, physiology, nutrition or biochemistry, you will need a strong base in organic chemistry.

Organic chemistry she says is much like mathematics - you are able to score 100% in an exam. She offers an important tip and that is to that in studying organic chemistry - you need to start at the basics and build your way up as you learn. If you go stepwise, you will be on the right track.

Here is an example.

In order to solve a problem in Organic Chemistry, remember it is important to go stepwise as shown below:

Problem: What two products are possible from the addition of HBr to 1-propene?

Step1
Write the structure of 1-propene. It is advisable to write a condensed structure and then bond-line if you are not familiar with the bond line structures. Count the carbons and place the double bond at the correct position. Recall that 1-propene is an unsymmetrical alkene.


Step2
HBr, the attacking reagent is made up of H+ and Br-. These two species attack at the double bond of the alkene.

Step 3
Now recall the Markovnikov's rule - When an unsymmetric reagent adds to an unsymmetric alkene, the electropositive part of the reagent bonds to the carbon of the double bond that has the greater number of hydrogen atoms attached to it.

Step 4
Draw the major and minor products and name them according to IUPAC rules. Find the longest chain. Find the substituents and their location and accordingly name the haloalkane.
The two possible products are:


More information:

Article by Deepa S. Mahajan
Basic Sciences Department, Botswana College of Agriculture, P Bag 0027,
Gaborone. Botswana; dmahajan@bca.bw

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